Determination of Trace Amounts of Thallium by Adsorptive Cathodic Stripping Voltammetry with Xylenol Orange.

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Determination of trace amounts of thallium by adsorptive cathodic stripping voltammetry with xylenol orange.

Trace amounts of thallium(I) can be determined using adsorptive cathodic stripping voltammetry in the presence of Xylenol Orange (XO). The reduction current of the thallium(I)-XO complex ion was measured by square-wave cathodic stripping voltammetry. The peak potential was at -0.44 V vs. Ag/AgCl. The effect of various parameters (pH, ligand concentration, accumulation potential and collection t...

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Determination of trace amounts of lead by adsorptive cathodic stripping voltammetry in the presence of xylenol orange

Lead forms the complexes with xylenol orange in the basic solution. An adsorptivedifferential pulse stripping method for the determination of lead is proposed. The procedureinvolves an adsorptive accumulation of lead on a hanging mercury drop electrode (HMDE) inthe presence of xylenol orange, followed by reduction of adsorbed lead by voltammetric scanusing differential pulse modulation. The opt...

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determination of trace amounts of lead by adsorptive cathodic stripping voltammetry in the presence of xylenol orange

lead forms the complexes with xylenol orange in the basic solution. an adsorptivedifferential pulse stripping method for the determination of lead is proposed. the procedureinvolves an adsorptive accumulation of lead on a hanging mercury drop electrode (hmde) inthe presence of xylenol orange, followed by reduction of adsorbed lead by voltammetric scanusing differential pulse modulation. the opt...

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Simultaneous Determination of Trace Amounts of Lead and Zinc by Adsorptive Cathodic Stripping Voltammetry

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A method for the determination of nickel(II) by stripping voltammetry is described. The method is based on the adsorptive accumulation of nickel(II) calconcarboxylic acid complex onto a hanging mercury drop electrode (HMDE), followed by the reduction of the adsorbed complex using differential pulse voltammetry. The optimum operating conditions and parameters were found to be 0.05 M NH3/NH4Cl bu...

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ژورنال

عنوان ژورنال: Analytical Sciences

سال: 2002

ISSN: 0910-6340,1348-2246

DOI: 10.2116/analsci.18.993